Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini

Borate glass with fluoride ions has diverse applications in solar energy converters, lasers, infrared fibre optics, and electronic devices. Exploring the mixed alkali effect in borate glass is crucial for identify its potential. Therefore, this study aims to investigate the optical, elastic, electri...

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Main Author:	Muhamad Sahapini, Noor Fadhilah
Format:	Thesis
Language:	English
Published:	2024
Subjects:	Composite materials Radiation physics (General)
Online Access:	https://ir.uitm.edu.my/id/eprint/102213/1/102213.pdf
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spelling	my-uitm-ir.1022132024-12-05T06:31:25Z Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini 2024 Muhamad Sahapini, Noor Fadhilah Composite materials Radiation physics (General) Borate glass with fluoride ions has diverse applications in solar energy converters, lasers, infrared fibre optics, and electronic devices. Exploring the mixed alkali effect in borate glass is crucial for identify its potential. Therefore, this study aims to investigate the optical, elastic, electrical, and radiation shielding properties of xBaF2–(50 – x)CaF250B2O3 (x = 5 – 35 mol%) mixed alkaline earth borate glass. Glass samples were synthesised via melt-quenching technique, confirmed as amorphous through X-ray diffraction (XRD) analysis. FTIR spectroscopy revealed BO3 conversion to B4 units. The addition of BaF2 increased molar volume (Vm) and density (ρ) except at 25 mol% BaF2, due to mixed alkaline earth effect (MAEE) and extensive non bridging oxygen (NBO) formation, supported by the abrupt decrease of N4. The increase in the optical band gap (Eopt), describing the weakening of the glass structure. Anomaly at 20 mol% BaF2 in refractive index (n) and optical band gap (Eopt) variation, linked to the role of MAEE. The elastic velocities, shear (S) and young (Y) modulus decreased with (x ≤ 30 mol%), aligned with structural findings. However, the longitudinal (L) and bulk (Ke) modulus had minima at 10 and 25 mol%, coincided with Urbach Energy (Eu) maxima, indicating increased in structural randomness. Makishima-Mackenzie Model aligned with the experimental values, exhibiting a sudden drop at 25 mol%, due to dissociation bond energy decrease. Bulk compression model proposed isotropic deformation, affecting network bond lengths and sizes while keeping interatomic bond angles unchanged. The ring deformation model indicated isotropic ring compression due to bending between structural units. The anomaly at 25 mol% correlated with the variation of σDC against composition. The conductivity initially decreased (x < 20 mol%) due to the blocking effects of larger Ba2+ ions against Ca2+. However, an abrupt increase occurred at 25 mol%, indicating enhanced charge mobility. The temperature and frequency dependence of σAC suggested the Overlapping Large Polaron Tunneling (OLPT) model dominated as the main transport mechanism. Besides, the dielectric constant (ε') was more prominent in low-frequency regions, signifying that the space charge polarisation as main polarisation. Anomalies at 10 mol% and 25 mol% on ε', supported the elastic data. In the radiation shielding study, adding BaF2 to the glass samples increased the effective atomic number, thereby enhancing their potential for radiation attenuation. Among the various glass samples, the composition containing 25 mol% BaF2 displayed the smallest values for MFP and HVL, indicating its superior effectiveness in photon attenuation. Therefore, this composition can be considered as a preferable option among the glass samples for gamma protection applications. 2024 Thesis https://ir.uitm.edu.my/id/eprint/102213/ https://ir.uitm.edu.my/id/eprint/102213/1/102213.pdf text en public phd doctoral Universiti Teknologi MARA (UiTM) Faculty of Applied Science
institution	Universiti Teknologi MARA
collection	UiTM Institutional Repository
language	English
topic	Composite materials Radiation physics (General)
spellingShingle	Composite materials Radiation physics (General) Muhamad Sahapini, Noor Fadhilah Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini
description	Borate glass with fluoride ions has diverse applications in solar energy converters, lasers, infrared fibre optics, and electronic devices. Exploring the mixed alkali effect in borate glass is crucial for identify its potential. Therefore, this study aims to investigate the optical, elastic, electrical, and radiation shielding properties of xBaF2–(50 – x)CaF250B2O3 (x = 5 – 35 mol%) mixed alkaline earth borate glass. Glass samples were synthesised via melt-quenching technique, confirmed as amorphous through X-ray diffraction (XRD) analysis. FTIR spectroscopy revealed BO3 conversion to B4 units. The addition of BaF2 increased molar volume (Vm) and density (ρ) except at 25 mol% BaF2, due to mixed alkaline earth effect (MAEE) and extensive non bridging oxygen (NBO) formation, supported by the abrupt decrease of N4. The increase in the optical band gap (Eopt), describing the weakening of the glass structure. Anomaly at 20 mol% BaF2 in refractive index (n) and optical band gap (Eopt) variation, linked to the role of MAEE. The elastic velocities, shear (S) and young (Y) modulus decreased with (x ≤ 30 mol%), aligned with structural findings. However, the longitudinal (L) and bulk (Ke) modulus had minima at 10 and 25 mol%, coincided with Urbach Energy (Eu) maxima, indicating increased in structural randomness. Makishima-Mackenzie Model aligned with the experimental values, exhibiting a sudden drop at 25 mol%, due to dissociation bond energy decrease. Bulk compression model proposed isotropic deformation, affecting network bond lengths and sizes while keeping interatomic bond angles unchanged. The ring deformation model indicated isotropic ring compression due to bending between structural units. The anomaly at 25 mol% correlated with the variation of σDC against composition. The conductivity initially decreased (x < 20 mol%) due to the blocking effects of larger Ba2+ ions against Ca2+. However, an abrupt increase occurred at 25 mol%, indicating enhanced charge mobility. The temperature and frequency dependence of σAC suggested the Overlapping Large Polaron Tunneling (OLPT) model dominated as the main transport mechanism. Besides, the dielectric constant (ε') was more prominent in low-frequency regions, signifying that the space charge polarisation as main polarisation. Anomalies at 10 mol% and 25 mol% on ε', supported the elastic data. In the radiation shielding study, adding BaF2 to the glass samples increased the effective atomic number, thereby enhancing their potential for radiation attenuation. Among the various glass samples, the composition containing 25 mol% BaF2 displayed the smallest values for MFP and HVL, indicating its superior effectiveness in photon attenuation. Therefore, this composition can be considered as a preferable option among the glass samples for gamma protection applications.
format	Thesis
qualification_name	Doctor of Philosophy (PhD.)
qualification_level	Doctorate
author	Muhamad Sahapini, Noor Fadhilah
author_facet	Muhamad Sahapini, Noor Fadhilah
author_sort	Muhamad Sahapini, Noor Fadhilah
title	Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini
title_short	Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini
title_full	Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini
title_fullStr	Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini
title_full_unstemmed	Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini
title_sort	optical, elastic, electrical, and radiation shielding properties of xbaf2-(50-x)caf2-50b203 mixed alkaline earth borate glasses / noor fadhilah muhamad sahapini
granting_institution	Universiti Teknologi MARA (UiTM)
granting_department	Faculty of Applied Science
publishDate	2024
url	https://ir.uitm.edu.my/id/eprint/102213/1/102213.pdf
_version_	1818588037004656640

Optical, elastic, electrical, and radiation shielding properties of xBaF2-(50-x)CaF2-50B203 mixed alkaline earth borate glasses / Noor Fadhilah Muhamad Sahapini

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