Elastic and structural studies on (95-x)TeO₂-5La₂O₃-xTiO₂ lanthanum tellurite and xLi₂O-(100-X)[0.65GeO₂.O35PbO]lead germanate glasses / Izyan Nuraini Sapian

Lanthanum tellurite and lead germanate glasses with compositions (95-x)TeO₂-5La₂O₃-xTiO₂ (x = 0 mol% to 20 mol%) and xLi₂O-(100-X)[0.65GeO₂.O35PbO] (x = 0 mol% to 40 mol%) were prepared by the melt quenching method, respectively. Elastic and structural properties of the glasses were studied by measu...

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Main Author: Sapian, Izyan Nuraini
Format: Thesis
Language:English
Published: 2016
Online Access:https://ir.uitm.edu.my/id/eprint/18484/2/TM_IZYAN%20NURAINI%20SAPIAN%20AS%2016_5.pdf
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spelling my-uitm-ir.184842021-12-01T09:10:09Z Elastic and structural studies on (95-x)TeO₂-5La₂O₃-xTiO₂ lanthanum tellurite and xLi₂O-(100-X)[0.65GeO₂.O35PbO]lead germanate glasses / Izyan Nuraini Sapian 2016 Sapian, Izyan Nuraini Lanthanum tellurite and lead germanate glasses with compositions (95-x)TeO₂-5La₂O₃-xTiO₂ (x = 0 mol% to 20 mol%) and xLi₂O-(100-X)[0.65GeO₂.O35PbO] (x = 0 mol% to 40 mol%) were prepared by the melt quenching method, respectively. Elastic and structural properties of the glasses were studied by measuring sound velocity using the pulse-echo-overlap technique and Fourier Transform Infrared (FTIR) spectroscopy, respectively. For (95-x)TeO₂-5La₂O₃-xTiO₂ (x = 0 mol% to 20 mol%) samples, ultrasonic velocity measurements showed both independent moduli (Cʟ and μ ) and related elastic moduli such as bulk modulus (Kₑ), Young's modulus, hardness and Debye temperature were observed to increase gradually for x < 15 mol% followed by a large increase at x = 20 mol% addition of TiO₂. The results obtained showed that this glass system becomes more stable, rigid and stiffer with addition of TiC>2. Structural analysis showed increase in bridging-oxygen (BO) compared to non-bridging oxygen (NBO). Differential Scanning Calorimetry (DSC) measurements showed Tg increased with addition of TiO₂ and confirms the increasing rigidity of the network… 2016 Thesis https://ir.uitm.edu.my/id/eprint/18484/ https://ir.uitm.edu.my/id/eprint/18484/2/TM_IZYAN%20NURAINI%20SAPIAN%20AS%2016_5.pdf text en public mphil masters Universiti Teknologi MARA Faculty of Applied Sciences
institution Universiti Teknologi MARA
collection UiTM Institutional Repository
language English
description Lanthanum tellurite and lead germanate glasses with compositions (95-x)TeO₂-5La₂O₃-xTiO₂ (x = 0 mol% to 20 mol%) and xLi₂O-(100-X)[0.65GeO₂.O35PbO] (x = 0 mol% to 40 mol%) were prepared by the melt quenching method, respectively. Elastic and structural properties of the glasses were studied by measuring sound velocity using the pulse-echo-overlap technique and Fourier Transform Infrared (FTIR) spectroscopy, respectively. For (95-x)TeO₂-5La₂O₃-xTiO₂ (x = 0 mol% to 20 mol%) samples, ultrasonic velocity measurements showed both independent moduli (Cʟ and μ ) and related elastic moduli such as bulk modulus (Kₑ), Young's modulus, hardness and Debye temperature were observed to increase gradually for x < 15 mol% followed by a large increase at x = 20 mol% addition of TiO₂. The results obtained showed that this glass system becomes more stable, rigid and stiffer with addition of TiC>2. Structural analysis showed increase in bridging-oxygen (BO) compared to non-bridging oxygen (NBO). Differential Scanning Calorimetry (DSC) measurements showed Tg increased with addition of TiO₂ and confirms the increasing rigidity of the network…
format Thesis
qualification_name Master of Philosophy (M.Phil.)
qualification_level Master's degree
author Sapian, Izyan Nuraini
spellingShingle Sapian, Izyan Nuraini
Elastic and structural studies on (95-x)TeO₂-5La₂O₃-xTiO₂ lanthanum tellurite and xLi₂O-(100-X)[0.65GeO₂.O35PbO]lead germanate glasses / Izyan Nuraini Sapian
author_facet Sapian, Izyan Nuraini
author_sort Sapian, Izyan Nuraini
title Elastic and structural studies on (95-x)TeO₂-5La₂O₃-xTiO₂ lanthanum tellurite and xLi₂O-(100-X)[0.65GeO₂.O35PbO]lead germanate glasses / Izyan Nuraini Sapian
title_short Elastic and structural studies on (95-x)TeO₂-5La₂O₃-xTiO₂ lanthanum tellurite and xLi₂O-(100-X)[0.65GeO₂.O35PbO]lead germanate glasses / Izyan Nuraini Sapian
title_full Elastic and structural studies on (95-x)TeO₂-5La₂O₃-xTiO₂ lanthanum tellurite and xLi₂O-(100-X)[0.65GeO₂.O35PbO]lead germanate glasses / Izyan Nuraini Sapian
title_fullStr Elastic and structural studies on (95-x)TeO₂-5La₂O₃-xTiO₂ lanthanum tellurite and xLi₂O-(100-X)[0.65GeO₂.O35PbO]lead germanate glasses / Izyan Nuraini Sapian
title_full_unstemmed Elastic and structural studies on (95-x)TeO₂-5La₂O₃-xTiO₂ lanthanum tellurite and xLi₂O-(100-X)[0.65GeO₂.O35PbO]lead germanate glasses / Izyan Nuraini Sapian
title_sort elastic and structural studies on (95-x)teo₂-5la₂o₃-xtio₂ lanthanum tellurite and xli₂o-(100-x)[0.65geo₂.o35pbo]lead germanate glasses / izyan nuraini sapian
granting_institution Universiti Teknologi MARA
granting_department Faculty of Applied Sciences
publishDate 2016
url https://ir.uitm.edu.my/id/eprint/18484/2/TM_IZYAN%20NURAINI%20SAPIAN%20AS%2016_5.pdf
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