Development and characterization of lithium ion solid composite electrolytes prepared by sol gel / Hafizul Mat

Solid Composite Electrolytes (SCE) was developed, with LiC104 and LiNCb as the host material in composition with metal oxide, Si d to enhance the conductivity and the lithium transference number. SCE were sintered at 200 °C by using simple sol-gel method to remove the excess water with help of aceti...

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Main Author: Mat, Hafizul
Format: Thesis
Language:English
Published: 2017
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Online Access:https://ir.uitm.edu.my/id/eprint/37990/1/37990.pdf
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spelling my-uitm-ir.379902022-09-14T13:43:08Z Development and characterization of lithium ion solid composite electrolytes prepared by sol gel / Hafizul Mat 2017 Mat, Hafizul Electricity and magnetism Lithium cells Solid Composite Electrolytes (SCE) was developed, with LiC104 and LiNCb as the host material in composition with metal oxide, Si d to enhance the conductivity and the lithium transference number. SCE were sintered at 200 °C by using simple sol-gel method to remove the excess water with help of acetic acid as a binder between the interphase of host matrices and the metal oxide. SCE was then tested by using X-Ray Diffractogram (XRD), Field Emission Scanning Electron Microscope (FESEM) and Electrical Impedance Spectroscopy (EIS) to observe the physical properties of SCE in room temperature and also in high temperature. The highest conductivity of SCE is by using LiN03 as host matrix and SiCte as metal oxide which is 9.74 x 10"4 S/cm at room temperature with lower activation energy at higher temperature. Compared to LiC104- Si02, the conductivity of SCE is seemed too low compare with LiN03-Si02 but higher in lithium ion number which is 0.58. Existence of new lattice in XRD diffractogram caused the decrease in ion mobile and caused the ion mobile is anion. The enhancement of conductivity of the SCEs is depended on the amorphous phase of the samples that will create the ion pathways and increase the lithium ion number 2017 Thesis https://ir.uitm.edu.my/id/eprint/37990/ https://ir.uitm.edu.my/id/eprint/37990/1/37990.pdf text en public masters Universiti Teknologi MARA (UiTM) Faculty of Applied Sciences Yahaya Subban, Ri Hanum Mohamed, Nor Sabirin
institution Universiti Teknologi MARA
collection UiTM Institutional Repository
language English
advisor Yahaya Subban, Ri Hanum
Mohamed, Nor Sabirin
topic Electricity and magnetism
Lithium cells
spellingShingle Electricity and magnetism
Lithium cells
Mat, Hafizul
Development and characterization of lithium ion solid composite electrolytes prepared by sol gel / Hafizul Mat
description Solid Composite Electrolytes (SCE) was developed, with LiC104 and LiNCb as the host material in composition with metal oxide, Si d to enhance the conductivity and the lithium transference number. SCE were sintered at 200 °C by using simple sol-gel method to remove the excess water with help of acetic acid as a binder between the interphase of host matrices and the metal oxide. SCE was then tested by using X-Ray Diffractogram (XRD), Field Emission Scanning Electron Microscope (FESEM) and Electrical Impedance Spectroscopy (EIS) to observe the physical properties of SCE in room temperature and also in high temperature. The highest conductivity of SCE is by using LiN03 as host matrix and SiCte as metal oxide which is 9.74 x 10"4 S/cm at room temperature with lower activation energy at higher temperature. Compared to LiC104- Si02, the conductivity of SCE is seemed too low compare with LiN03-Si02 but higher in lithium ion number which is 0.58. Existence of new lattice in XRD diffractogram caused the decrease in ion mobile and caused the ion mobile is anion. The enhancement of conductivity of the SCEs is depended on the amorphous phase of the samples that will create the ion pathways and increase the lithium ion number
format Thesis
qualification_level Master's degree
author Mat, Hafizul
author_facet Mat, Hafizul
author_sort Mat, Hafizul
title Development and characterization of lithium ion solid composite electrolytes prepared by sol gel / Hafizul Mat
title_short Development and characterization of lithium ion solid composite electrolytes prepared by sol gel / Hafizul Mat
title_full Development and characterization of lithium ion solid composite electrolytes prepared by sol gel / Hafizul Mat
title_fullStr Development and characterization of lithium ion solid composite electrolytes prepared by sol gel / Hafizul Mat
title_full_unstemmed Development and characterization of lithium ion solid composite electrolytes prepared by sol gel / Hafizul Mat
title_sort development and characterization of lithium ion solid composite electrolytes prepared by sol gel / hafizul mat
granting_institution Universiti Teknologi MARA (UiTM)
granting_department Faculty of Applied Sciences
publishDate 2017
url https://ir.uitm.edu.my/id/eprint/37990/1/37990.pdf
_version_ 1783734446941274112