Effects of trivalent ion (Al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / Noriah Ab Wahab

Research related to Magnesium-Ion Batteries for application in energy storage devices focusing on developing all solid-state batteries becomes subject of interest in achieving a safe and environmentally energy storage device. However, Magnesium-Ion Batteries are facing lower ionic conductivity compa...

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Main Author: Ab Wahab, Noriah
Format: Thesis
Language:English
Published: 2023
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Online Access:https://ir.uitm.edu.my/id/eprint/91042/1/91042.pdf
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spelling my-uitm-ir.910422024-07-22T03:28:42Z Effects of trivalent ion (Al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / Noriah Ab Wahab 2023 Ab Wahab, Noriah Q Science (General) Physical and theoretical chemistry Research related to Magnesium-Ion Batteries for application in energy storage devices focusing on developing all solid-state batteries becomes subject of interest in achieving a safe and environmentally energy storage device. However, Magnesium-Ion Batteries are facing lower ionic conductivity compared to Lithium-ion Batteries. Hence, this research is presented to investigate the effects of Al3+ substitution on the structural, electrical and electrochemical properties of the Mgo.sTi2(P04)3 compound in enhancing the conductivity of the compound. Herein, NASICON-based framework structure, Mgo.5Ti2(P04)3 was developed as a potential material electrolyte focusing on the solid electrolytes. This research is divided into two (2) parts. The first part is to study the effects of heat treatment at different sintering temperatures (650, 700, 750, 800, 850, 900 and 950 °C) on the parent compound Mgo.sTi2(P04)3 while the second part is to study the effects of trivalent ion, Al3+ at different composition (x = 0.1, 0.3, 0.5, 0.7 and 0.9) in Mgo.5+o.5xAlxTi2-x(P04)3 compound. The sample of Mgo.sTi2(P04)3 parent compound was successfully synthesized via sol-gel method at different sintering temperatures with the same sintering duration (24 hours). Then, the structural, electrical and electrochemical properties of the compound were determined. 2023 Thesis https://ir.uitm.edu.my/id/eprint/91042/ https://ir.uitm.edu.my/id/eprint/91042/1/91042.pdf text en public masters Universiti Teknologi MARA (UiTM) Faculty of Applied Sciences Mustaffa, Nur Amalina
institution Universiti Teknologi MARA
collection UiTM Institutional Repository
language English
advisor Mustaffa, Nur Amalina
topic Q Science (General)
Physical and theoretical chemistry
spellingShingle Q Science (General)
Physical and theoretical chemistry
Ab Wahab, Noriah
Effects of trivalent ion (Al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / Noriah Ab Wahab
description Research related to Magnesium-Ion Batteries for application in energy storage devices focusing on developing all solid-state batteries becomes subject of interest in achieving a safe and environmentally energy storage device. However, Magnesium-Ion Batteries are facing lower ionic conductivity compared to Lithium-ion Batteries. Hence, this research is presented to investigate the effects of Al3+ substitution on the structural, electrical and electrochemical properties of the Mgo.sTi2(P04)3 compound in enhancing the conductivity of the compound. Herein, NASICON-based framework structure, Mgo.5Ti2(P04)3 was developed as a potential material electrolyte focusing on the solid electrolytes. This research is divided into two (2) parts. The first part is to study the effects of heat treatment at different sintering temperatures (650, 700, 750, 800, 850, 900 and 950 °C) on the parent compound Mgo.sTi2(P04)3 while the second part is to study the effects of trivalent ion, Al3+ at different composition (x = 0.1, 0.3, 0.5, 0.7 and 0.9) in Mgo.5+o.5xAlxTi2-x(P04)3 compound. The sample of Mgo.sTi2(P04)3 parent compound was successfully synthesized via sol-gel method at different sintering temperatures with the same sintering duration (24 hours). Then, the structural, electrical and electrochemical properties of the compound were determined.
format Thesis
qualification_level Master's degree
author Ab Wahab, Noriah
author_facet Ab Wahab, Noriah
author_sort Ab Wahab, Noriah
title Effects of trivalent ion (Al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / Noriah Ab Wahab
title_short Effects of trivalent ion (Al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / Noriah Ab Wahab
title_full Effects of trivalent ion (Al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / Noriah Ab Wahab
title_fullStr Effects of trivalent ion (Al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / Noriah Ab Wahab
title_full_unstemmed Effects of trivalent ion (Al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / Noriah Ab Wahab
title_sort effects of trivalent ion (al3+) substitution on the structural, electrical and electrochemical properties of magnesium titanium phosphate ceramic electrolytes / noriah ab wahab
granting_institution Universiti Teknologi MARA (UiTM)
granting_department Faculty of Applied Sciences
publishDate 2023
url https://ir.uitm.edu.my/id/eprint/91042/1/91042.pdf
_version_ 1811768756017299456