Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon

The limited source of raw materials for production of activated carbon has increased the price of commercial activated carbon price. Due to the presence of lignin and cellulose in sea mango make it as new potential for activated carbon. Sea mango activated carbon was prepared by chemical activati...

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Format:	Thesis
Language:	English
Subjects:	Carbon Activated Cerbera Sea Mango
Online Access:	http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/1/Page%201-24.pdf http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/2/Full%20Text.pdf http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/4/Nur%20Azira.pdf
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spelling	my-unimap-778952023-04-04T02:04:35Z Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon Nor Fauziah, Zainudin The limited source of raw materials for production of activated carbon has increased the price of commercial activated carbon price. Due to the presence of lignin and cellulose in sea mango make it as new potential for activated carbon. Sea mango activated carbon was prepared by chemical activation using potassium hydroxide (KOH) at different carbonization temperatures, which are 500ºC (AC500) and 600ºC (AC600) under nitrogen (N2) gas flow. The activated carbon prepared together with sea mango precursor (SMP) was characterized using Scanning Electron Microscope (SEM) and Brunaer Emmet Teller (BET) for surface morphology and specific surface area, respectively. The result showed that the surface of AC500 and AC600 has undergone some alteration where some new pores were developed. The specific surface area measured for SMP, AC500 and AC600 were 0.03 m2/g, 108.79 m2/g and 451.87m2/g, respectively. Fourier Transform Infrared Spectroscopy (FTIR) use to analyse functional group showed band transition between the three samples which indicated that chemical transformation had occurred during activation process. Analysis of Total Ash Content (TAS) has shown that the ash content increased in both AC500 (38.97%) and AC600 (41.82%) compared to SMP (2.53%) whereas AC500 has better yield compared to AC600. In order to study the performance of sea mango activated carbon, AC600 was further used in adsorption of Basic Red 46 dye in batch process. The effects of operating parameters, initial pH solution, adsorbent dosage, initial dye concentration and adsorption temperature were varied where the result obtained indicated that all parameters have played important roles in the adsorption process. High initial dye concentration has resulted in low adsorption of Basic Red 46 dye with the best initial pH solution was 11. It was found that the removal of Basic Red 46 dye increased with the increasing amount of adsorbent dosage and adsorption temperature. Interaction between parameters was studied using Response Surface Methodology (RSM). The optimum parameters were recorded at 150 mg/L initial dye concentration, initial pH solution of 11.00 and 1.00 g/L adsorbent dosage with R2 of 0.9943. Moreover, from the isotherm and kinetic analysis conducted, the results showed a monolayer adsorption as the data fitted well on Langmuir isotherm model and pseudo-second-order kinetic model with R2 values closed to 1. Universiti Malaysia Perlis (UniMAP) Thesis en http://dspace.unimap.edu.my:80/xmlui/handle/123456789/77895 http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/3/license.txt 8a4605be74aa9ea9d79846c1fba20a33 http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/1/Page%201-24.pdf 2c6150bf3d1c0e646e3c36c8c1825906 http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/2/Full%20Text.pdf 50950256d904167adba20e9ce689d0e5 http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/4/Nur%20Azira.pdf 22e043e5c32c3c37114454d0605995d9 Universiti Malaysia Perlis (UniMAP) Carbon, Activated Cerbera Sea Mango School of Bioprocess Engineering
institution	Universiti Malaysia Perlis
collection	UniMAP Institutional Repository
language	English
advisor	Nor Fauziah, Zainudin
topic	Carbon Activated Cerbera Sea Mango
spellingShingle	Carbon Activated Cerbera Sea Mango Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon
description	The limited source of raw materials for production of activated carbon has increased the price of commercial activated carbon price. Due to the presence of lignin and cellulose in sea mango make it as new potential for activated carbon. Sea mango activated carbon was prepared by chemical activation using potassium hydroxide (KOH) at different carbonization temperatures, which are 500ºC (AC500) and 600ºC (AC600) under nitrogen (N2) gas flow. The activated carbon prepared together with sea mango precursor (SMP) was characterized using Scanning Electron Microscope (SEM) and Brunaer Emmet Teller (BET) for surface morphology and specific surface area, respectively. The result showed that the surface of AC500 and AC600 has undergone some alteration where some new pores were developed. The specific surface area measured for SMP, AC500 and AC600 were 0.03 m2/g, 108.79 m2/g and 451.87m2/g, respectively. Fourier Transform Infrared Spectroscopy (FTIR) use to analyse functional group showed band transition between the three samples which indicated that chemical transformation had occurred during activation process. Analysis of Total Ash Content (TAS) has shown that the ash content increased in both AC500 (38.97%) and AC600 (41.82%) compared to SMP (2.53%) whereas AC500 has better yield compared to AC600. In order to study the performance of sea mango activated carbon, AC600 was further used in adsorption of Basic Red 46 dye in batch process. The effects of operating parameters, initial pH solution, adsorbent dosage, initial dye concentration and adsorption temperature were varied where the result obtained indicated that all parameters have played important roles in the adsorption process. High initial dye concentration has resulted in low adsorption of Basic Red 46 dye with the best initial pH solution was 11. It was found that the removal of Basic Red 46 dye increased with the increasing amount of adsorbent dosage and adsorption temperature. Interaction between parameters was studied using Response Surface Methodology (RSM). The optimum parameters were recorded at 150 mg/L initial dye concentration, initial pH solution of 11.00 and 1.00 g/L adsorbent dosage with R2 of 0.9943. Moreover, from the isotherm and kinetic analysis conducted, the results showed a monolayer adsorption as the data fitted well on Langmuir isotherm model and pseudo-second-order kinetic model with R2 values closed to 1.
format	Thesis
title	Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon
title_short	Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon
title_full	Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon
title_fullStr	Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon
title_full_unstemmed	Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon
title_sort	adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon
granting_institution	Universiti Malaysia Perlis (UniMAP)
granting_department	School of Bioprocess Engineering
url	http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/1/Page%201-24.pdf http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/2/Full%20Text.pdf http://dspace.unimap.edu.my:80/xmlui/bitstream/123456789/77895/4/Nur%20Azira.pdf
_version_	1776104251665154048

Adsorption of basic red 46 dye using sea mango (cerbera odollam) activated carbon

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