Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction

High temperature superconductors (HTSC) of microcrystalline ceramic material ErBa2Cu3O7-δ (ErBCO) have been successfully synthesized via co-precipitation (COP) using metal acetate precursors, and conventional solid state method (SS). Comparisons were made on the superconducting properties and electr...

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Main Author:	Nazarudin, Muhammad Farhan
Format:	Thesis
Language:	English English
Published:	2011
Subjects:	Electrochemistry Superconductors Ceramic materials
Online Access:	http://psasir.upm.edu.my/id/eprint/25919/1/FS%202011%2051R.pdf
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spelling	my-upm-ir.259192022-01-26T05:10:42Z Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction 2011-12 Nazarudin, Muhammad Farhan High temperature superconductors (HTSC) of microcrystalline ceramic material ErBa2Cu3O7-δ (ErBCO) have been successfully synthesized via co-precipitation (COP) using metal acetate precursors, and conventional solid state method (SS). Comparisons were made on the superconducting properties and electrochemical behavior of ErBCO from both methods. Resistivity versus temperature measurements (R-T) showed that all samples exhibited very good metallic behavior. For the COP samples, the sintering temperature was varied from 920-950 °C with the best zero critical current, TC(R=0) = 91.4 K obtained for the sample sintered at 920oC. The TC(R=0) = 90.9 K was obtained for the SS sample sintered at the same temperature. X-ray diffraction (XRD) data showed single phase samples of an orthorhombic structure. The formation of non superconducting phases (impurities) was observed when the COP samples were sintered above 920oC. Scanning electron micrographs (SEM) showed grains of size ≤ 40 nm were randomly distributed for all highly compacted samples. However, sample prepared via COP exhibited smaller pores as compared with SS sample. The electrochemical behaviour of the samples had been studied by the cyclic voltammetry (CV), chronoamperometry (CA) and chronocoulometry (CC) techniques. The samples were mechanically attached to glassy carbon (GC) electrode and immersed in NH4Cl electrolyte solution. NH4Cl electrolyte was chosen because it has a ligand bearing group with strong complexing ability with copper ion. Multiple cycling tests were carried out to observe the reproducibility and stability of the superconducting surface against the electrolyte. Four characteristics peaks were detected in cyclic voltammogram of ErBCO. There were two sets of peaks observed which could be attributed to the Cu2+/Cu1+ and Cu1+/Cu0 redox couples. This showed that the copper planes in the superconductor played a major role in the surface electrochemical processes. The cyclic voltammetric behavior exhibited from both samples was found to be affected by concentration, temperature and pH of the electrolyte. From CA and CC studies, diffusion coefficient, D was 3.4516 x 10-3cm2/s for COP and 2.3677 x 10-4cm2/s for SS respectively while the amount of charge, Q adsorbed on the electrode surface was 5.4413 μC/ cm2 for COP and 4.7383 μC/ cm2 for SS, respectively. Electrochemistry Superconductors Ceramic materials 2011-12 Thesis http://psasir.upm.edu.my/id/eprint/25919/ http://psasir.upm.edu.my/id/eprint/25919/1/FS%202011%2051R.pdf application/pdf en public masters Universiti Putra Malaysia Electrochemistry Superconductors Ceramic materials Faculty of Science English
institution	Universiti Putra Malaysia
collection	PSAS Institutional Repository
language	English English
topic	Electrochemistry Superconductors Ceramic materials
spellingShingle	Electrochemistry Superconductors Ceramic materials Nazarudin, Muhammad Farhan Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction
description	High temperature superconductors (HTSC) of microcrystalline ceramic material ErBa2Cu3O7-δ (ErBCO) have been successfully synthesized via co-precipitation (COP) using metal acetate precursors, and conventional solid state method (SS). Comparisons were made on the superconducting properties and electrochemical behavior of ErBCO from both methods. Resistivity versus temperature measurements (R-T) showed that all samples exhibited very good metallic behavior. For the COP samples, the sintering temperature was varied from 920-950 °C with the best zero critical current, TC(R=0) = 91.4 K obtained for the sample sintered at 920oC. The TC(R=0) = 90.9 K was obtained for the SS sample sintered at the same temperature. X-ray diffraction (XRD) data showed single phase samples of an orthorhombic structure. The formation of non superconducting phases (impurities) was observed when the COP samples were sintered above 920oC. Scanning electron micrographs (SEM) showed grains of size ≤ 40 nm were randomly distributed for all highly compacted samples. However, sample prepared via COP exhibited smaller pores as compared with SS sample. The electrochemical behaviour of the samples had been studied by the cyclic voltammetry (CV), chronoamperometry (CA) and chronocoulometry (CC) techniques. The samples were mechanically attached to glassy carbon (GC) electrode and immersed in NH4Cl electrolyte solution. NH4Cl electrolyte was chosen because it has a ligand bearing group with strong complexing ability with copper ion. Multiple cycling tests were carried out to observe the reproducibility and stability of the superconducting surface against the electrolyte. Four characteristics peaks were detected in cyclic voltammogram of ErBCO. There were two sets of peaks observed which could be attributed to the Cu2+/Cu1+ and Cu1+/Cu0 redox couples. This showed that the copper planes in the superconductor played a major role in the surface electrochemical processes. The cyclic voltammetric behavior exhibited from both samples was found to be affected by concentration, temperature and pH of the electrolyte. From CA and CC studies, diffusion coefficient, D was 3.4516 x 10-3cm2/s for COP and 2.3677 x 10-4cm2/s for SS respectively while the amount of charge, Q adsorbed on the electrode surface was 5.4413 μC/ cm2 for COP and 4.7383 μC/ cm2 for SS, respectively.
format	Thesis
qualification_level	Master's degree
author	Nazarudin, Muhammad Farhan
author_facet	Nazarudin, Muhammad Farhan
author_sort	Nazarudin, Muhammad Farhan
title	Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction
title_short	Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction
title_full	Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction
title_fullStr	Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction
title_full_unstemmed	Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction
title_sort	electrochemical characteristic of erba2cu3o7-8 superconductor synthesized via co-precipitation and solid-state reaction
granting_institution	Universiti Putra Malaysia
granting_department	Faculty of Science
publishDate	2011
url	http://psasir.upm.edu.my/id/eprint/25919/1/FS%202011%2051R.pdf
_version_	1747811532427755520

Electrochemical characteristic of ErBa2Cu3O7-8 superconductor synthesized via co-precipitation and solid-state reaction

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