Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes

The research described in this thesis focuses on the synthesis and characterization of four new Schiff butyl- (or hexyl-) S-substituted Schiff bases. S-alkyl-β-N-(p-methoxyphenyl)methylenedithiocarbazate (MSBu/MSHe) and S-alkyl-β-N-(p–nitrophenyl)methylenedithiocarbazate (NSBu/NSHe) formed by conden...

Full description

Saved in:

Bibliographic Details
Main Author:	Rusli, Aqilah Fasihah
Format:	Thesis
Language:	English
Published:	2015
Subjects:	Transition metals Metal complexes Transition metal complexes
Online Access:	http://psasir.upm.edu.my/id/eprint/85443/1/FS%202015%2093%20ir.pdf
Tags:	Add Tag No Tags, Be the first to tag this record!

id	my-upm-ir.85443
record_format	uketd_dc
spelling	my-upm-ir.854432021-12-16T02:40:18Z Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes 2015-06 Rusli, Aqilah Fasihah The research described in this thesis focuses on the synthesis and characterization of four new Schiff butyl- (or hexyl-) S-substituted Schiff bases. S-alkyl-β-N-(p-methoxyphenyl)methylenedithiocarbazate (MSBu/MSHe) and S-alkyl-β-N-(p–nitrophenyl)methylenedithiocarbazate (NSBu/NSHe) formed by condensation reaction of newly synthesized S-butyldithiocarbazate and S-hexyldithiocarbazate, with 4-methoxybenzaldehyde and 4-nitrobenzaldehyde and their transition metal complexes. Complexes of copper(II), nickel(II), zinc(II) and cadmium(II) were synthesized in 2:1 mole ratio (Schiff base: metal) in ethanol. All compounds were characterized using various physico-chemical techniques and spectroscopic methods. Single crystal X-ray analysis was carried out on S-methyl-β-N-(p-methoxyphenyl)methylenedithiocarbazate and its copper (II) and nickel (II) complexes, Cu[MSBu]2 and Ni[MSBu]2 as well as the nickel (II) complex of S-hexyl-β-N-(p-methoxyphenyl)methylenedithiocarbazate, Ni[NSHe]2. The Schiff base MSBu, Ni[MSBu]2 and Ni[NSHe]2 crystallized in the triclinic system with the space group of P -1. Cu[MSBu]2 complex crystallizes in the monoclinic space group P 1 21/c 1. The Cu(II) and Ni(II) complexes are four coordinate with trans square-planar configuration with the Schiff base acting as a bidentate chelating agent coordinated via the azomethine nitrogen and thiolate sulphur atom. Although for Zn(II) and Cd(II) efforts to obtain single crystal were not successful, elemental analyses and spectroscopic data indicate that they also adopt four-coordinated structures. Transition metals Metal complexes Transition metal complexes 2015-06 Thesis http://psasir.upm.edu.my/id/eprint/85443/ http://psasir.upm.edu.my/id/eprint/85443/1/FS%202015%2093%20ir.pdf text en public masters Universiti Putra Malaysia Transition metals Metal complexes Transition metal complexes Crouse, Karen Ann
institution	Universiti Putra Malaysia
collection	PSAS Institutional Repository
language	English
advisor	Crouse, Karen Ann
topic	Transition metals Metal complexes Transition metal complexes
spellingShingle	Transition metals Metal complexes Transition metal complexes Rusli, Aqilah Fasihah Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes
description	The research described in this thesis focuses on the synthesis and characterization of four new Schiff butyl- (or hexyl-) S-substituted Schiff bases. S-alkyl-β-N-(p-methoxyphenyl)methylenedithiocarbazate (MSBu/MSHe) and S-alkyl-β-N-(p–nitrophenyl)methylenedithiocarbazate (NSBu/NSHe) formed by condensation reaction of newly synthesized S-butyldithiocarbazate and S-hexyldithiocarbazate, with 4-methoxybenzaldehyde and 4-nitrobenzaldehyde and their transition metal complexes. Complexes of copper(II), nickel(II), zinc(II) and cadmium(II) were synthesized in 2:1 mole ratio (Schiff base: metal) in ethanol. All compounds were characterized using various physico-chemical techniques and spectroscopic methods. Single crystal X-ray analysis was carried out on S-methyl-β-N-(p-methoxyphenyl)methylenedithiocarbazate and its copper (II) and nickel (II) complexes, Cu[MSBu]2 and Ni[MSBu]2 as well as the nickel (II) complex of S-hexyl-β-N-(p-methoxyphenyl)methylenedithiocarbazate, Ni[NSHe]2. The Schiff base MSBu, Ni[MSBu]2 and Ni[NSHe]2 crystallized in the triclinic system with the space group of P -1. Cu[MSBu]2 complex crystallizes in the monoclinic space group P 1 21/c 1. The Cu(II) and Ni(II) complexes are four coordinate with trans square-planar configuration with the Schiff base acting as a bidentate chelating agent coordinated via the azomethine nitrogen and thiolate sulphur atom. Although for Zn(II) and Cd(II) efforts to obtain single crystal were not successful, elemental analyses and spectroscopic data indicate that they also adopt four-coordinated structures.
format	Thesis
qualification_level	Master's degree
author	Rusli, Aqilah Fasihah
author_facet	Rusli, Aqilah Fasihah
author_sort	Rusli, Aqilah Fasihah
title	Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes
title_short	Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes
title_full	Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes
title_fullStr	Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes
title_full_unstemmed	Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes
title_sort	synthesis and characterization of a new series of dithiocarbazato schiff bases and their transition metal complexes
granting_institution	Universiti Putra Malaysia
publishDate	2015
url	http://psasir.upm.edu.my/id/eprint/85443/1/FS%202015%2093%20ir.pdf
_version_	1747813541557043200

Synthesis and characterization of a new series of Dithiocarbazato schiff bases and their transition metal complexes

Similar Items