Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique

Porous carbonated hydroxyapatite (C-HAP) was successfully fabricated by a sponge template and carbonation technique from micron-sized commercial HAP powders and synthesized nano-sized HAP powders. The carbonation of the porous HAP, performed during the cooling stage of the sintering process under w...

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Main Author:	., Sunarso
Format:	Thesis
Language:	English
Published:	2012
Subjects:	TA404 Composite materials
Online Access:	http://eprints.usm.my/41133/1/SUNARSO_24_Pages.pdf
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id	my-usm-ep.41133
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spelling	my-usm-ep.411332018-07-23T07:41:05Z Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique 2012 ., Sunarso TA404 Composite materials Porous carbonated hydroxyapatite (C-HAP) was successfully fabricated by a sponge template and carbonation technique from micron-sized commercial HAP powders and synthesized nano-sized HAP powders. The carbonation of the porous HAP, performed during the cooling stage of the sintering process under wet carbon dioxide (CO2) gas, was successful in incorporating CO3 2- ions into porous HAP. Carbonation was carried out at three different cooling temperatures (200, 300 and 400oC) and flow times (20, 40 and 60min). The optimum condition for carbonation in terms of CO3 2- content was obtained after the gas had been passed through at a cooling temperature of 200oC for 60min. It was found that an increase in cooling temperature resulted in a decrease in CO3 2- ion content, whilst a longer flow time yielded in an increase of CO3 2- ion content. Mg(NO3)2, which was equivalent to 1, 3, 5 and 7 wt% of MgO, was added to enhance the mechanical strength of porous C-HAP. The compressive strength of porous C-HAP reached the highest value after an addition of Mg(NO3)2 equivalent to 1 wt% of MgO. It was observed that the porous C-HAP fabricated from nanoemulsion-derived HAP powders possessed a higher CO3 2- ion content (1.70 wt%) compared to that of porous C-HAP fabricated from micron-sized commercial HAP powders (1.25 wt%), indicating that the smaller particle size of the starting material might have enhanced the reactivity of the porous specimens to CO2 gas during carbonation. After immersion in SBF solution for 1, 2 and 4 weeks at 36.5±1.0oC, apatite-like layer grew faster in the porous C-HAP with higher CO3 2- ion content, suggesting that the carbonation technique used in this study was able to enhance the bioactivity performance of the porous product. 2012 Thesis http://eprints.usm.my/41133/ http://eprints.usm.my/41133/1/SUNARSO_24_Pages.pdf application/pdf en public masters Universiti Sains Malaysia Pusat Pengajian Kejuruteraan Bahan dan Sumber Mineral
institution	Universiti Sains Malaysia
collection	USM Institutional Repository
language	English
topic	TA404 Composite materials
spellingShingle	TA404 Composite materials ., Sunarso Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique
description	Porous carbonated hydroxyapatite (C-HAP) was successfully fabricated by a sponge template and carbonation technique from micron-sized commercial HAP powders and synthesized nano-sized HAP powders. The carbonation of the porous HAP, performed during the cooling stage of the sintering process under wet carbon dioxide (CO2) gas, was successful in incorporating CO3 2- ions into porous HAP. Carbonation was carried out at three different cooling temperatures (200, 300 and 400oC) and flow times (20, 40 and 60min). The optimum condition for carbonation in terms of CO3 2- content was obtained after the gas had been passed through at a cooling temperature of 200oC for 60min. It was found that an increase in cooling temperature resulted in a decrease in CO3 2- ion content, whilst a longer flow time yielded in an increase of CO3 2- ion content. Mg(NO3)2, which was equivalent to 1, 3, 5 and 7 wt% of MgO, was added to enhance the mechanical strength of porous C-HAP. The compressive strength of porous C-HAP reached the highest value after an addition of Mg(NO3)2 equivalent to 1 wt% of MgO. It was observed that the porous C-HAP fabricated from nanoemulsion-derived HAP powders possessed a higher CO3 2- ion content (1.70 wt%) compared to that of porous C-HAP fabricated from micron-sized commercial HAP powders (1.25 wt%), indicating that the smaller particle size of the starting material might have enhanced the reactivity of the porous specimens to CO2 gas during carbonation. After immersion in SBF solution for 1, 2 and 4 weeks at 36.5±1.0oC, apatite-like layer grew faster in the porous C-HAP with higher CO3 2- ion content, suggesting that the carbonation technique used in this study was able to enhance the bioactivity performance of the porous product.
format	Thesis
qualification_level	Master's degree
author	., Sunarso
author_facet	., Sunarso
author_sort	., Sunarso
title	Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique
title_short	Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique
title_full	Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique
title_fullStr	Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique
title_full_unstemmed	Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique
title_sort	fabrication of porous carbonated hydroxyapatite by a sponge template and carbonation technique
granting_institution	Universiti Sains Malaysia
granting_department	Pusat Pengajian Kejuruteraan Bahan dan Sumber Mineral
publishDate	2012
url	http://eprints.usm.my/41133/1/SUNARSO_24_Pages.pdf
_version_	1747820880223797248

Fabrication Of Porous Carbonated Hydroxyapatite By A Sponge Template And Carbonation Technique

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