Synthesis, Characterization, Nucleolytic, Antibacterial And Antiproliferative Properties Of Vanadium, Copper And Manganese Complexes

Series of vanadium carboxylato complexes, copper carboxylato complexes, manganese carboxylato complexes and vanadium phenanthroline derivative complexes have been synthesized and characterized. The details of all the complexes are tabulated in Table 2.2 (page 37). The complexes have been characteri...

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Bibliographic Details
Main Author: Lim, Eng Khoon
Format: Thesis
Language:English
Published: 2011
Subjects:
Online Access:http://eprints.usm.my/43371/1/LIM%20ENG%20KHOON.pdf
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Summary:Series of vanadium carboxylato complexes, copper carboxylato complexes, manganese carboxylato complexes and vanadium phenanthroline derivative complexes have been synthesized and characterized. The details of all the complexes are tabulated in Table 2.2 (page 37). The complexes have been characterized by X-ray crystallography, elemental analysis, FT-IR, UV–Vis spectroscopy and cyclic voltammetry. In electrochemistry studies, vanadium carboxylato complexes show redox active by displaying a quasireversible redox couple corresponding to VV/VIV redox process while copper carboxylato complexes show redox active by displaying two quasi-reversible redox couples corresponding to CuIICuII/CuIICuI and CuIICuI/CuICuI redox processes and manganese carboxylato complexes show redox active by displaying a quasi-reversible redox couple corresponding to MnII/MnIII redox process.