Synthesis And Anisotropic Properties Of Liquid Crystal Dimers Consisting Of Ester And Disulphide Bridging Groups
Four new series of dimers consist of ester and disulphide bridging groups have been synthesized and the anisotropic properties for each dimer characterized. These series comprise of two non-symmetric dimers which are α-{4-[(4-substituted-phenylimino)methyl]carbonyl)phenoxy]phenoxy}-ω-[4-(4-(R,S)-2-m...
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my-usm-ep.435952019-04-12T05:26:11Z Synthesis And Anisotropic Properties Of Liquid Crystal Dimers Consisting Of Ester And Disulphide Bridging Groups 2013-07 Osman, Faridah QD1-999 Chemistry Four new series of dimers consist of ester and disulphide bridging groups have been synthesized and the anisotropic properties for each dimer characterized. These series comprise of two non-symmetric dimers which are α-{4-[(4-substituted-phenylimino)methyl]carbonyl)phenoxy]phenoxy}-ω-[4-(4-(R,S)-2-methylbutyloxy carbonylphenyl)phenoxy]hexanoate, X-E6-RSMB and α-{4-[(4-substituted-phenyl imino)methyl]carbonyl)phenoxy]phenoxy}-ω-[4-(4-(S)-2-methylbutyloxycarbonyl phenyl)phenoxy]hexanoate, X-E6-SMB and also the other two symmetric dimers (6-{4-[(4-substituted-phenylimino)methyl]phenoxy}hexyl)disulphide, X-6-SS-6-X and (6-{4-[(4-bromophenylimino)methyl]phenoxy}alkyl)disulphide, Br-n-SS-n-Br. The differences between the two series of non-symmetric dimers can be attributed to the presence of various terminal substituents and the introduction of chiral and racemic centres at the biphenyl fragments. For both series of symmetrical dimers the differences can be attributed to the variety of the spacer length and terminal substituents. 2013-07 Thesis http://eprints.usm.my/43595/ http://eprints.usm.my/43595/1/Faridah%20Binti%20Osman24.pdf application/pdf en public masters Universiti Sains Malaysia Pusat Pengajian Sains Kimia |
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QD1-999 Chemistry |
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QD1-999 Chemistry Osman, Faridah Synthesis And Anisotropic Properties Of Liquid Crystal Dimers Consisting Of Ester And Disulphide Bridging Groups |
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Four new series of dimers consist of ester and disulphide bridging groups have been synthesized and the anisotropic properties for each dimer characterized. These series comprise of two non-symmetric dimers which are α-{4-[(4-substituted-phenylimino)methyl]carbonyl)phenoxy]phenoxy}-ω-[4-(4-(R,S)-2-methylbutyloxy carbonylphenyl)phenoxy]hexanoate, X-E6-RSMB and α-{4-[(4-substituted-phenyl imino)methyl]carbonyl)phenoxy]phenoxy}-ω-[4-(4-(S)-2-methylbutyloxycarbonyl phenyl)phenoxy]hexanoate, X-E6-SMB and also the other two symmetric dimers (6-{4-[(4-substituted-phenylimino)methyl]phenoxy}hexyl)disulphide, X-6-SS-6-X and (6-{4-[(4-bromophenylimino)methyl]phenoxy}alkyl)disulphide, Br-n-SS-n-Br. The differences between the two series of non-symmetric dimers can be attributed to the presence of various terminal substituents and the introduction of chiral and racemic centres at the biphenyl fragments. For both series of symmetrical dimers the differences can be attributed to the variety of the spacer length and terminal substituents. |
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Thesis |
qualification_level |
Master's degree |
author |
Osman, Faridah |
author_facet |
Osman, Faridah |
author_sort |
Osman, Faridah |
title |
Synthesis And Anisotropic Properties Of Liquid Crystal Dimers Consisting Of Ester And Disulphide Bridging Groups |
title_short |
Synthesis And Anisotropic Properties Of Liquid Crystal Dimers Consisting Of Ester And Disulphide Bridging Groups |
title_full |
Synthesis And Anisotropic Properties Of Liquid Crystal Dimers Consisting Of Ester And Disulphide Bridging Groups |
title_fullStr |
Synthesis And Anisotropic Properties Of Liquid Crystal Dimers Consisting Of Ester And Disulphide Bridging Groups |
title_full_unstemmed |
Synthesis And Anisotropic Properties Of Liquid Crystal Dimers Consisting Of Ester And Disulphide Bridging Groups |
title_sort |
synthesis and anisotropic properties of liquid crystal dimers consisting of ester and disulphide bridging groups |
granting_institution |
Universiti Sains Malaysia |
granting_department |
Pusat Pengajian Sains Kimia |
publishDate |
2013 |
url |
http://eprints.usm.my/43595/1/Faridah%20Binti%20Osman24.pdf |
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1747821244006268928 |