A comparative study on wear and corrosion behaviour of tungsten carbide-nickel (Wc-Ni) and tungsten carbide-cobalt (Wc-Co) high velocity oxy-fuel (HVOF) for carbon steel blade

Nowadays, the demand of high wear and corrosion resistance of the components in various industry is increasing from time to time. Therefore, high velocity oxy-fuel (HVOF) thermal spray was introduced to protect machine components from wear and corrosion, to restore worn components and to improve the...

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Main Author: Ahmad, Noor Aqilah
Format: Thesis
Language:English
English
English
Published: 2017
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spelling my-uthm-ep.8382021-09-06T02:48:48Z A comparative study on wear and corrosion behaviour of tungsten carbide-nickel (Wc-Ni) and tungsten carbide-cobalt (Wc-Co) high velocity oxy-fuel (HVOF) for carbon steel blade 2017-08 Ahmad, Noor Aqilah TA401-492 Materials of engineering and construction. Mechanics of materials Nowadays, the demand of high wear and corrosion resistance of the components in various industry is increasing from time to time. Therefore, high velocity oxy-fuel (HVOF) thermal spray was introduced to protect machine components from wear and corrosion, to restore worn components and to improve the durability of the components. HVOF is one of the process of depositing a material layer over a base metal or substrate with characteristics of high flame velocity and moderate temperature. The main purpose of this present study is to characterize the structure of the tungsten carbide 10 wt.% nickel (WC-10Ni) and tungsten carbide 12 wt.% w cobalt (WC-12Co) coating deposited by means of HVOF thermal spray onto a continuous digester (CD) blade that made up from carbon steel. The morphology and chemical composition of the coating were characterized by scanning electron microscope (SEM), electron dispersive spectrometer (EDS), and x-ray diffraction (XRD). The hardness test was carried out by using Vickers micro-hardness tester with load of 490.3 mN (0.05 HV). The wear and corrosion behavior and mechanism for both coatings was compared. Three body wear test was carried out in term of weight loss and electrochemical test was performed in acidic media (mixture of sulfuric acid, H2SO4 and ilmenite) to obtain the corrosion rate of the coating. From the result, it shows that WC-12Co coating has finer grain size that is around 2.3 μm. WC-12Co has higher wear resistance due to high volume friction, low mean free path, high hardness and lower porosity distribution compared to WC-10Ni. Besides, the formation of secondary phase, W2C also affected the hardness of both coating, where this phase is harder than WC phase. For corrosion test, WC-12Co shows good corrosion resistance with small differences of corrison rate with WC-10Ni, that is only 0.7016 mm/y. As a conclusion, WC-12Co HVOF coating shows high potential on replacement of CD blade. 2017-08 Thesis http://eprints.uthm.edu.my/838/ http://eprints.uthm.edu.my/838/1/24p%20NOOR%20AQILAH%20AHMAD.pdf text en public http://eprints.uthm.edu.my/838/2/NOOR%20AQILAH%20AHMAD%20COPYRIGHT%20DECLARATION.pdf text en staffonly http://eprints.uthm.edu.my/838/3/NOOR%20AQILAH%20AHMAD%20WATERMARK.pdf text en validuser mphil masters Universiti Tun Hussein Onn Malaysia Fakulti Kejuruteraan Mekanikal dan Pembuatan
institution Universiti Tun Hussein Onn Malaysia
collection UTHM Institutional Repository
language English
English
English
topic TA401-492 Materials of engineering and construction
Mechanics of materials
spellingShingle TA401-492 Materials of engineering and construction
Mechanics of materials
Ahmad, Noor Aqilah
A comparative study on wear and corrosion behaviour of tungsten carbide-nickel (Wc-Ni) and tungsten carbide-cobalt (Wc-Co) high velocity oxy-fuel (HVOF) for carbon steel blade
description Nowadays, the demand of high wear and corrosion resistance of the components in various industry is increasing from time to time. Therefore, high velocity oxy-fuel (HVOF) thermal spray was introduced to protect machine components from wear and corrosion, to restore worn components and to improve the durability of the components. HVOF is one of the process of depositing a material layer over a base metal or substrate with characteristics of high flame velocity and moderate temperature. The main purpose of this present study is to characterize the structure of the tungsten carbide 10 wt.% nickel (WC-10Ni) and tungsten carbide 12 wt.% w cobalt (WC-12Co) coating deposited by means of HVOF thermal spray onto a continuous digester (CD) blade that made up from carbon steel. The morphology and chemical composition of the coating were characterized by scanning electron microscope (SEM), electron dispersive spectrometer (EDS), and x-ray diffraction (XRD). The hardness test was carried out by using Vickers micro-hardness tester with load of 490.3 mN (0.05 HV). The wear and corrosion behavior and mechanism for both coatings was compared. Three body wear test was carried out in term of weight loss and electrochemical test was performed in acidic media (mixture of sulfuric acid, H2SO4 and ilmenite) to obtain the corrosion rate of the coating. From the result, it shows that WC-12Co coating has finer grain size that is around 2.3 μm. WC-12Co has higher wear resistance due to high volume friction, low mean free path, high hardness and lower porosity distribution compared to WC-10Ni. Besides, the formation of secondary phase, W2C also affected the hardness of both coating, where this phase is harder than WC phase. For corrosion test, WC-12Co shows good corrosion resistance with small differences of corrison rate with WC-10Ni, that is only 0.7016 mm/y. As a conclusion, WC-12Co HVOF coating shows high potential on replacement of CD blade.
format Thesis
qualification_name Master of Philosophy (M.Phil.)
qualification_level Master's degree
author Ahmad, Noor Aqilah
author_facet Ahmad, Noor Aqilah
author_sort Ahmad, Noor Aqilah
title A comparative study on wear and corrosion behaviour of tungsten carbide-nickel (Wc-Ni) and tungsten carbide-cobalt (Wc-Co) high velocity oxy-fuel (HVOF) for carbon steel blade
title_short A comparative study on wear and corrosion behaviour of tungsten carbide-nickel (Wc-Ni) and tungsten carbide-cobalt (Wc-Co) high velocity oxy-fuel (HVOF) for carbon steel blade
title_full A comparative study on wear and corrosion behaviour of tungsten carbide-nickel (Wc-Ni) and tungsten carbide-cobalt (Wc-Co) high velocity oxy-fuel (HVOF) for carbon steel blade
title_fullStr A comparative study on wear and corrosion behaviour of tungsten carbide-nickel (Wc-Ni) and tungsten carbide-cobalt (Wc-Co) high velocity oxy-fuel (HVOF) for carbon steel blade
title_full_unstemmed A comparative study on wear and corrosion behaviour of tungsten carbide-nickel (Wc-Ni) and tungsten carbide-cobalt (Wc-Co) high velocity oxy-fuel (HVOF) for carbon steel blade
title_sort comparative study on wear and corrosion behaviour of tungsten carbide-nickel (wc-ni) and tungsten carbide-cobalt (wc-co) high velocity oxy-fuel (hvof) for carbon steel blade
granting_institution Universiti Tun Hussein Onn Malaysia
granting_department Fakulti Kejuruteraan Mekanikal dan Pembuatan
publishDate 2017
url http://eprints.uthm.edu.my/838/1/24p%20NOOR%20AQILAH%20AHMAD.pdf
http://eprints.uthm.edu.my/838/2/NOOR%20AQILAH%20AHMAD%20COPYRIGHT%20DECLARATION.pdf
http://eprints.uthm.edu.my/838/3/NOOR%20AQILAH%20AHMAD%20WATERMARK.pdf
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