Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater

Polypyrrole-magnetite (PPy-Fe3O4) dispersive micro-solid phase extraction (PPy-Fe3O4-D-μ-SPE) method combined with ultraviolet-visible (UV-Vis) spectrophotometry was developed for the determination of the selected basic dyes in textile wastewater. PPy-Fe3O4 was used as adsorbent due to its stability...

Full description

Saved in:

Bibliographic Details
Main Author:	Kamaruddin, Amirah Farhan
Format:	Thesis
Language:	English
Published:	2017
Subjects:	QD Chemistry
Online Access:	http://eprints.utm.my/id/eprint/78476/1/AmirahFarhanKamaruddinMFS2017.pdf
Tags:	Add Tag No Tags, Be the first to tag this record!

id	my-utm-ep.78476
record_format	uketd_dc
spelling	my-utm-ep.784762018-08-26T11:56:27Z Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater 2017-04 Kamaruddin, Amirah Farhan QD Chemistry Polypyrrole-magnetite (PPy-Fe3O4) dispersive micro-solid phase extraction (PPy-Fe3O4-D-μ-SPE) method combined with ultraviolet-visible (UV-Vis) spectrophotometry was developed for the determination of the selected basic dyes in textile wastewater. PPy-Fe3O4 was used as adsorbent due to its stability and excellent conductivity as well as capable of adsorbing the studied dyes. Two basic dyes, Rhodamine 6G (Rh 6G) and Crystal Violet (CV) were chosen as model compounds. Several important D-μ-SPE parameters were evaluated and optimized including sample pH, amount of adsorbent, extraction time and type of desorption solvents. The optimum PPy-Fe3O4-D-μ-SPE conditions were sample solution pH 8, 60 mg of PPy-Fe3O4 adsorbent, 5 min of extraction time and acetonitrile as the desorption solvent. Under the optimized conditions, PPy-Fe3O4-D-μ-SPE method showed good linearity in the range of 0.05-7 mg/L with coefficient of determination R2 > 0.998. The method showed good limit of detection (LOD) for the basic dyes (0.05 mg/L) and good analyte recoveries (97.4 to 111.3%) with relative standard deviations (RSD) < 10%. The developed method was successfully applied to the analysis of real textile wastewater where the concentration found was 1.03±7.9% mg/L and 1.13±4.6% mg/L for Rh 6G and CV respectively. From the result, it can be concluded that PPy-Fe3O4-D-μ-SPE method can be adopted for the extraction and analysis of trace level basic dyes in short time (total analysis time < 15 min). 2017-04 Thesis http://eprints.utm.my/id/eprint/78476/ http://eprints.utm.my/id/eprint/78476/1/AmirahFarhanKamaruddinMFS2017.pdf application/pdf en public http://dms.library.utm.my:8080/vital/access/manager/Repository/vital:109696 masters Universiti Teknologi Malaysia, Faculty of Science Faculty of Science
institution	Universiti Teknologi Malaysia
collection	UTM Institutional Repository
language	English
topic	QD Chemistry
spellingShingle	QD Chemistry Kamaruddin, Amirah Farhan Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater
description	Polypyrrole-magnetite (PPy-Fe3O4) dispersive micro-solid phase extraction (PPy-Fe3O4-D-μ-SPE) method combined with ultraviolet-visible (UV-Vis) spectrophotometry was developed for the determination of the selected basic dyes in textile wastewater. PPy-Fe3O4 was used as adsorbent due to its stability and excellent conductivity as well as capable of adsorbing the studied dyes. Two basic dyes, Rhodamine 6G (Rh 6G) and Crystal Violet (CV) were chosen as model compounds. Several important D-μ-SPE parameters were evaluated and optimized including sample pH, amount of adsorbent, extraction time and type of desorption solvents. The optimum PPy-Fe3O4-D-μ-SPE conditions were sample solution pH 8, 60 mg of PPy-Fe3O4 adsorbent, 5 min of extraction time and acetonitrile as the desorption solvent. Under the optimized conditions, PPy-Fe3O4-D-μ-SPE method showed good linearity in the range of 0.05-7 mg/L with coefficient of determination R2 > 0.998. The method showed good limit of detection (LOD) for the basic dyes (0.05 mg/L) and good analyte recoveries (97.4 to 111.3%) with relative standard deviations (RSD) < 10%. The developed method was successfully applied to the analysis of real textile wastewater where the concentration found was 1.03±7.9% mg/L and 1.13±4.6% mg/L for Rh 6G and CV respectively. From the result, it can be concluded that PPy-Fe3O4-D-μ-SPE method can be adopted for the extraction and analysis of trace level basic dyes in short time (total analysis time < 15 min).
format	Thesis
qualification_level	Master's degree
author	Kamaruddin, Amirah Farhan
author_facet	Kamaruddin, Amirah Farhan
author_sort	Kamaruddin, Amirah Farhan
title	Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater
title_short	Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater
title_full	Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater
title_fullStr	Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater
title_full_unstemmed	Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater
title_sort	polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6g and crystal violet in textile wastewater
granting_institution	Universiti Teknologi Malaysia, Faculty of Science
granting_department	Faculty of Science
publishDate	2017
url	http://eprints.utm.my/id/eprint/78476/1/AmirahFarhanKamaruddinMFS2017.pdf
_version_	1747817993995288576

Polypyrrole-magnetite dispersive micro-solid phase extraction for the determination of rhodamine 6G and crystal violet in textile wastewater

Similar Items